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107 107 107 110 111 112 VI The Photoeyelization Process . . . . . . . A Formation of 4a,4b-Dihydrophenanthrenes . . . . . B Kinetic and Mechanistic Studies of the Photocyclization . . . Triplet State Photocyclization . . . . . . . C Structural Effects on Photocyclization Reactivity . . . . a Electronic Effects . . . . . . . . 1 Substituent Effects . . . . . . . . 2 Hetero-atom Effects . . . . . . . . 3 Electrostatic Repulsion Effects . . .
Free Radicals in Solution, New York: Wiley 1957. For a recent MINDO/3 study supporting this interpretation see Dewar, M. J. S. , J. Am. Chem. Soc. 100, 5290 (1978) 91. Summaries at Beckwith, A. , Essays in Free Radical Chemistry Norman, R. O. C. ed. Chemical Society, Special Publ. : Pure and AppL Chem. 15, 167 (1967); Nonhebel, D. , Walton, J. : Free Radical Chemistry, p. 533ff. Cambridge: University Press 1974 92. Clark, D. , Scanlan, J. , Walton, J. : Chem. Phy~ Lett. 53, 102 (1978) 93. Tedder, J.
C. ed. Chemical Society, Special Publ. : Pure and AppL Chem. 15, 167 (1967); Nonhebel, D. , Walton, J. : Free Radical Chemistry, p. 533ff. Cambridge: University Press 1974 92. Clark, D. , Scanlan, J. , Walton, J. : Chem. Phy~ Lett. 53, 102 (1978) 93. Tedder, J. , Walton, J. : Aec. Chem. Research 9, 183 (1976) 94. Brown, H. : Organic Synthesis via Boranes, New York: Wiley 1975; Davies, D. , Parrott, J. , Free Radicals in Organic Synthesis, Berlin-Heidelberg-New York: Springer 1978 95. : Chem. Ber.