Alkene Metathesis in Organic Synthesis by Alois Fuerstner

By Alois Fuerstner

Content material: Olefin metathesis by means of well-defined complexes of molybdenum and tungsten / R.R.Schrock -- Ruthenium-catalyzed metathesis reactions in natural synthesis / A. Furstner -- Ring-closing metathesis within the synthesis of epothilones and polyether traditional items / K.C. Nicolaou, N.P. King, Y. He -- Catalytic ring-closing metathesis and the improvement of enantioselective procedures / A.H. Hoveyda -- Enyne metathesis / M. Mori -- Cross-metathesis / Susan E. Gibson, S.P. prepared -- contemporary advances in ADMET chemistry / D. Tindall, J.H. Pawlow and K.B. Wagener -- Bioactive polymers / L.L. Kiessling, L.E. powerful

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Moreover, water soluble catalysts have been developed that contain bulky aliphatic phosphine ligands with either a quarternary ammonium group (1f,g) or a sulfonate function (1h) [12]. They have been tested in the ring opening polymerization Ruthenium-Catalyzed Metathesis Reactions in Organic Synthesis 41 Fig. 2 Scheme 4. (ROMP) of functionalized oxanorbornenes in water, methanol and aqueous emulsions, but have not yet been used in RCM. The overall mechanism of RCM is generally believed to proceed via the alternating series of formal [2+2] cycloaddition/cycloreversion steps outlined in Scheme 4 (Chauvin mechanism) [1, 13], although many details concerning the structure and properties of the intermediates A–D involved in this catalytic cycle are not yet fully resolved.

Thanks the National Science Foundation for supporting fundamental studies of complexes containing multiple metal–carbon bonds, Olefin Metathesis by Well-Defined Complexes of Molybdenum and Tungsten 31 the Navy for supporting studies in ring-opening metathesis polymerization, the Department of Energy for supporting studies in the synthesis of polyenes, and the graduate and postdoctoral students who have contributed their time, energy, and talent. 12 References 1. Ivin KJ, Mol JC (1997) Olefin metathesis and metathesis polymerization.

Metathesis Reactions in Solid Phase Synthesis . . . 46 51 51 58 59 4 Olefin Metathesis in Supercritical Carbon Dioxide . . . . . 59 . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 A. Fürstner 5 Selected Applications of RCM to Target Oriented Synthesis . . . 6 Carbocyclic Nucleosides . . . . . . . . . . Manzamine A . . . . . . . . . . . . . Epothilone A . . . . . . . . . . . . . (+)-Lasiodiplodin . . . . . .

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